Open AccessA photoreactive crystalline quasiracemate
Author(s) -
R.C. Grove,
S.H. Malehorn,
Meghan E. Breen,
Kraig A. Wheeler
Publication year - 2010
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c0cc02775h
Subject(s) - supramolecular chemistry , chemistry , combinatorial chemistry , stereochemistry , crystallography , crystal structure
Rationally designed racemic and quasiracemic sulfonamidecinnamic acids assemble to give hydrogen-bonded dimers with coplanar alignment of neighboring olefins. The quasiracemate phase contains near inversion-related motifs with chemically distinct components forming supramolecular heterodimers that undergo asymmetric photodimerization.
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