Molecular tectonics: crystal engineering of mixed valence Fe(ii)/Fe(iii) solid solutions | Zendy

Pierre Dechambenoit | Zendy; Sylvie Ferlay | Zendy; Nathalie Kyritsakas | Zendy; Mir Wais Hosseini | Zendy

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Molecular tectonics: crystal engineering of mixed valence Fe(ii)/Fe(iii) solid solutions

Author(s) -

Pierre Dechambenoit,

Sylvie Ferlay,

Nathalie Kyritsakas,

Mir Wais Hosseini

Publication year - 2009

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/b919478a

Subject(s) - valence (chemistry) , crystallography , chemistry , solid solution , crystal (programming language) , composite number , materials science , organic chemistry , composite material , computer science , programming language

Based on isostructurality between crystals formed upon combining the dicationic tecton 2 with either M(3)Fe(III)(CN)(6) or M(4)Fe(II)(CN)(6) (M = Cs), a rare example of an H-bonded mixed valence Fe(ii)-Fe(iii) solid solution ((Cs(2)2(3)-[Fe(II)(CN)(6)](2))(0.83)(2(3)-[Fe(III)(CN)(6)](2))(0.17))) and curious necklace-like composite crystals were generated.

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