Extended X-ray absorption fine structure (EXAFS) characterisation of dilute palladium homogeneous catalystsElectronic supplementary information (ESI) available: electronic supplementary data (ESI) available: data includes reaction profile for and structural/statistical data from EXAFS analysis of Pd(OAc)2/PBut3 catalysed Heck reaction. See http://www.rsc.org/suppdata/cc/b3/b307535d/ | Zendy

Steven G. Fiddy | Zendy; John Evans | Zendy; Mark A. Newton | Zendy; Thomas Neisius | Zendy; Robert P. Tooze | Zendy; R. J. Oldman | Zendy

Open Access

Extended X-ray absorption fine structure (EXAFS) characterisation of dilute palladium homogeneous catalystsElectronic supplementary information (ESI) available: electronic supplementary data (ESI) available: data includes reaction profile for and structural/statistical data from EXAFS analysis of Pd(OAc)2/PBut3 catalysed Heck reaction. See http://www.rsc.org/suppdata/cc/b3/b307535d/

Author(s) -

Steven G. Fiddy,

John Evans,

Mark A. Newton,

Thomas Neisius,

Robert P. Tooze,

R. J. Oldman

Publication year - 2003

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/b307535d

Subject(s) - extended x ray absorption fine structure , palladium , homogeneous , absorption (acoustics) , x ray absorption fine structure , electronic structure , materials science , chemistry , analytical chemistry (journal) , computational chemistry , catalysis , absorption spectroscopy , physics , statistical physics , optics , organic chemistry , spectroscopy , composite material , quantum mechanics

Highly dilute EXAFS characterisation for the elucidation of species involved in Heck chemistry is demonstrated; the major "monomer" species of Herrmann's acetate-bridged phosphapalladadacycle is characterised and species present during the course of a 50 ppm [Pd] Pd(OAc)2/PBu(t)3 catalysed Heck reaction are presented.

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