Charge assisted chiral hybrid H-bonded molecular networksElectronic supplementary information (ESI) available: synthetic details. See http://www.rsc.org/suppdata/cc/b3/b301467n/
Author(s) -
Sylvie Ferlay,
Roman Holakovský,
Mir Wais Hosseini,
J.-M. Planeix,
Nathalie Kyritsakas
Publication year - 2003
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/b301467n
Subject(s) - cationic polymerization , bridging (networking) , crystallography , crystallization , phase (matter) , materials science , chemistry , combinatorial chemistry , stereochemistry , polymer chemistry , organic chemistry , computer science , computer network
The co-crystallisation of [Fe(CN)5NO]2- and cyclic achiral 1(2+) and chiral 2(2+) or 3(2+) bisamidinium tectons leads in the crystalline phase to the formation of 1-D H-bonded achiral and chiral molecular networks respectively. In all cases, the network is formed by mutual bridging of the anionic and cationic units through a chelate mode of H-bonding.
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