Open AccessA novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement
Author(s) -
T. Khan,
Peter J. Skabara,
Simon J. Coles,
Michael B. Hursthouse
Publication year - 2001
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/b009550h
Subject(s) - allylic rearrangement , chemistry , aryl , diol , stereochemistry , perchloric acid , medicinal chemistry , combinatorial chemistry , catalysis , organic chemistry , alkyl
In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product
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