Open AccessIntegrated CO2 capture-fixation chemistry via interfacial ionic liquid catalyst in laminar gas/liquid flow
Author(s) -
Niraj Kumar Vishwakarma,
Ajay Singh,
Yonghwan Hwang,
Dong-Hyeon Ko,
Jin–Oh Kim,
A. Giridhar Babu,
DongPyo Kim
Publication year - 2017
Publication title -
nature communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.559
H-Index - 365
ISSN - 2041-1723
DOI - 10.1038/ncomms14676
Subject(s) - ionic liquid , laminar flow , microreactor , flow chemistry , catalysis , reagent , flue gas , chemical engineering , chemistry , nanotechnology , materials science , organic chemistry , thermodynamics , physics , engineering
Simultaneous capture of carbon dioxide (CO 2 ) and its utilization with subsequent work-up would significantly enhance the competitiveness of CO 2 -based sustainable chemistry over petroleum-based chemistry. Here we report an interfacial catalytic reaction platform for an integrated autonomous process of simultaneously capturing/fixing CO 2 in gas–liquid laminar flow with subsequently providing a work-up step. The continuous-flow microreactor has built-in silicon nanowires (SiNWs) with immobilized ionic liquid catalysts on tips of cone-shaped nanowire bundles. Because of the superamphiphobic SiNWs, a stable gas–liquid interface maintains between liquid flow of organoamines in upper part and gas flow of CO 2 in bottom part of channel. The intimate and direct contact of the binary reagents leads to enhanced mass transfer and facilitating reactions. The autonomous integrated platform produces and isolates 2-oxazolidinones and quinazolines-2,4(1 H ,3 H )-diones with 81–97% yields under mild conditions. The platform would enable direct CO 2 utilization to produce high-valued specialty chemicals from flue gases without pre-separation and work-up steps.