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Quantification of HCl from high resolution infrared solar spectra obtained at the South Pole in December 1986
Author(s) -
Goldman A.,
Murcray F. J.,
Murcray F. H.,
Murcray D. G.
Publication year - 1987
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1029/gl014i006p00622
Subject(s) - spectral line , infrared , high resolution , spectral resolution , infrared spectroscopy , atmospheric sciences , resolution (logic) , environmental science , non linear least squares , physics , geology , analytical chemistry (journal) , remote sensing , optics , chemistry , astronomy , mathematics , explained sum of squares , environmental chemistry , quantum mechanics , artificial intelligence , computer science , statistics
Ground‐based infrared solar spectra at 0.02 cm −1 resolution obtained at the Amundsen‐Scott South Pole station in December 1986 have been analysed for the atmospheric content of HCl. Nonlinear least‐squares spectral fitting applied to the spectra yields a total HCl column amount of (6.4 ± 0.8) × 10 15 molec/cm², most being stratospheric. This amount is larger than that extrapolated from earlier results on the latitudinal distribution of atmospheric HCl.

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