E.P.R. study of the reactivity of ClO with H 2 CO at 298 K | Zendy

Poulet Gilles | Zendy; Le Bras Georges | Zendy; Combourieu Jean | Zendy

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E.P.R. study of the reactivity of ClO with H 2 CO at 298 K

Author(s) -

Poulet Gilles,

Le Bras Georges,

Combourieu Jean

Publication year - 1980

Publication title -

geophysical research letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.007

H-Index - 273

eISSN - 1944-8007

pISSN - 0094-8276

DOI - 10.1029/gl007i005p00413

Subject(s) - reactivity (psychology) , radical , stratosphere , electron paramagnetic resonance , reaction rate constant , chemistry , analytical chemistry (journal) , nuclear magnetic resonance , physics , kinetics , atmospheric sciences , environmental chemistry , organic chemistry , medicine , alternative medicine , pathology , quantum mechanics

The reaction of ClO with H 2 CO has been studied by the discharge flow EPR technique. An upper limit of 10 −15 cm³ molecule −1 s −1 has been found for the rate constant at 298 K. Then this reaction cannot be a sink for ClO radicals in the stratosphere. Besides, evidence has been shown for a noticeable reactivity between ClO and HCO at 298 K.

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