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Non–aqueous phase liquid dissolution in heterogeneous systems: Mechanisms and a local equilibrium modeling approach
Author(s) -
Powers Susan E.,
Nambi Indumathi M.,
Curry Garrey W.
Publication year - 1998
Publication title -
water resources research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.863
H-Index - 217
eISSN - 1944-7973
pISSN - 0043-1397
DOI - 10.1029/98wr02471
Subject(s) - dissolution , saturation (graph theory) , mass transfer , thermodynamics , aqueous solution , work (physics) , materials science , mechanics , chemistry , physics , mathematics , combinatorics
Experiments quantifying rates of non–aqueous phase liquid (NAPL) dissolution from heterogeneous media are presented and compared with model simulations. This work specifically addresses the overall dissolution of NAPL entrapped in a coarse sand lens at a high saturation. To explore the mechanisms governing dissolution rates, mathematical models describing the hydrodynamics of flow through the heterogeneous system were developed and coupled with a mass balance equation and a local equilibrium assumption (LEA) to quantify interphase mass transfer processes. Variations in the effective permeabilities as a function of NAPL saturation and the intrinsic permeabilities of the sands were employed to characterize the hydrodynamic aspects of flow through the heterogeneous system. Relative to errors generated by the ill‐defined aqueous phase relative permeabilities at high NAPL saturations, the model incorporating the system hydrodynamics as the sole rate‐limiting process provided a reasonable first estimate of effluent concentrations. With the representative elemental volume defined here, rate‐limited dissolution becomes important for low‐NAPL saturations ( S n < ∼0.05–0.15) causing tailing in the observed dissolution data and deviations between these data and the LEA model.