Open AccessPhysical properties of stratospheric clouds during the Antarctic winter of 1995
Author(s) -
Gobbi Gian Paolo,
Di Donfrancesco Guido,
Adriani Alberto
Publication year - 1998
Publication title -
journal of geophysical research: atmospheres
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.67
H-Index - 298
eISSN - 2156-2202
pISSN - 0148-0227
DOI - 10.1029/98jd00280
Subject(s) - stratosphere , atmospheric sciences , lidar , polar , environmental science , backscatter (email) , ozone depletion , settling , mixed phase , mixing ratio , geology , phase (matter) , chemistry , physics , remote sensing , telecommunications , astronomy , environmental engineering , computer science , wireless , organic chemistry
Lidar observations collected during winter 1995 at McMurdo Station, Antarctica (78°S‐167°E), are analyzed to determine polar stratospheric cloud (PSC) physical properties. A scheme to infer PSC phase from lidar depolarization and backscatter profiles is presented. Interpretation is supported by collocated temperature soundings and by isentropic back trajectories. The analysis shows that first appearance of PSC is consistent with frozen sulfates, mixing with liquid ternary solutions (H 2 SO 4 ‐HNO 3 ‐H 2 O) when temperature lowers. Finally, solids consistent with HNO 3 mixing ratios form as mixed phases first, then followed by full solid phases. Mixed phases (i.e., coexisting solid and liquid aerosols) are detected during the whole winter. While mixed phase PSCs form particularly in the altitude range 15–20 km and are the last to disappear, full solid phases are mainly observed above 20 km and last until the end of August. Mixed phases possess the largest PSC surface areas and, as a result of selective growth, can reach large, fast settling sizes. The considerable denitrification and halogen activation observed in the Antarctic lower stratosphere, where the ozone hole takes place, appears to be well correlated with the action of this kind of PSC.