Premium
Stable chlorine isotopic composition of marine aerosol particles in the western Atlantic Ocean
Author(s) -
Volpe Christopher,
Spivack Arthur J.
Publication year - 1994
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1029/94gl01164
Subject(s) - chlorine , sea salt , aerosol , seawater , environmental chemistry , sulfate , sea salt aerosol , fractionation , sea spray , volatilisation , environmental science , atmospheric sciences , chemistry , oceanography , geology , organic chemistry
The isotopic composition of chlorine sampled from the atmosphere has been measured for the first time. Eight aerosol samples collected on bulk filters at Bermuda are enriched in 37 Cl relative to sea water. Stable chlorine isotopic compositions are reported in units of per mil as δ 37 Cl which is defined as 1000 × [( R sample / R sea water ) ‐ 1] where R is the ratio of 37 Cl to 35 Cl. The δ 37 Cl of the aerosols range from +0.42 to +2.53 per mil and strongly correlate with chlorine deficit (based upon sea salt sodium) and non‐sea salt sulfate. The data trend is consistent with the fractional distillation (loss) of HCl from an acidified aerosol governed by a fractionation factor of 0.9972. Subsequent experiments support the hypothesis that HCl evaporation was most likely the primary mechanism of chlorine volatilization in the sampled aerosols. Furthermore, the data indicate that marine aerosols perturbed by anthropogenic NOx and SO 2 are an important source of isotopically light chlorine in the free troposphere.