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The potential role of the ocean in regulating atmospheric CH 3 Br
Author(s) -
Butler James H.
Publication year - 1994
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1029/94gl00071
Subject(s) - atmosphere (unit) , environmental science , flux (metallurgy) , atmospheric sciences , range (aeronautics) , mixing ratio , meteorology , chemistry , geology , physics , materials science , organic chemistry , composite material
An increase or decrease in anthropogenic emissions of methyl bromide (CH 3 Br) will induce a compensating flux of this gas from the ocean to the atmosphere. This, in turn, will tend to lessen the expected change in atmospheric mixing ratio from that calculated in models that incorporate a constant oceanic source. To a first degree, this buffering effect by the ocean is independent of in situ oceanic production and land based sources. The partial lifetime of atmospheric CH 3 Br with respect to the ocean could reasonably range from 1.3 to 14 y, with a current best estimate of 3.7 y. This yields an effective atmospheric lifetime, which incorporates oceanic losses and thus can be used in simple, mass balance calculations of atmospheric CH 3 Br, of 1.2 y, with a probable range of 0.7 to 1.8 y.