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Hydrology and alkalinity regulation of soft Florida waters: An integrated assessment
Author(s) -
Stauffer Robert E.,
Canfield Daniel E.
Publication year - 1992
Publication title -
water resources research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.863
H-Index - 217
eISSN - 1944-7973
pISSN - 0043-1397
DOI - 10.1029/92wr00360
Subject(s) - hydrology (agriculture) , alkalinity , streams , water table , aquifer , groundwater recharge , geology , surficial aquifer , soil water , sulfate , watershed , groundwater , ridge , biogeochemical cycle , environmental science , soil science , ecology , chemistry , geotechnical engineering , organic chemistry , computer network , paleontology , materials science , machine learning , computer science , metallurgy , biology
Natural waters in ridge provinces of Florida and southeast Georgia were classified geographically, by degrees of cultural disturbance, and according to the dominant hydrologic and biogeochemical processes controlling chemistry. The ionic composition of lakes, upland streams, and surficial aquifer (water table) springs in relatively undeveloped catchments reflects the geographic variations in bulk deposition corrected for evapotranspiration (Na, Cl), plus a slight gain (net watershed mobilization) of Mg, and partial to nearly complete losses (net retention) of nitrate, sulfate, Ca, and K. Recharge to the Floridan aquifer in infertile, forested, sandy ridge provinces of northern Florida contains 360–580 μmol CO 2 . On the basis of indirect geochemical evidence, sulfate retention appears less important in lake sediments than in the region's highly weathered, ferruginous, kaolinitic, sand soils. Silica concentrations in upland streams and water table springs closely reflect the predicted equilibrium between kaolinite and gibbsite. Along with other evidence, the Si concentrations in ridge lakes indicate that seepage inflow is much more important than assumed in Baker et al.'s (1988) regional model. Lakes and streams are acidified either by humic acids or nonmarine sulfate but rarely by both, as reflected by the significant inverse correlation between these two components. Contrary to previous reports, there is no significant difference in alkalinity for culturally undisturbed lakes in the northern Trail versus southern Highlands Ridge areas.