A determination of the rate constant for the reaction of HOCL with O‐atoms at room temperature | Zendy

Vogt Rainer | Zendy; Schindler Ralph N. | Zendy

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A determination of the rate constant for the reaction of HOCL with O‐atoms at room temperature

Author(s) -

Vogt Rainer,

Schindler Ralph N.

Publication year - 1992

Publication title -

geophysical research letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.007

H-Index - 273

eISSN - 1944-8007

pISSN - 0094-8276

DOI - 10.1029/92gl02100

Subject(s) - reaction rate constant , constant (computer programming) , analytical chemistry (journal) , chemistry , reaction rate , volumetric flow rate , thermodynamics , physics , environmental chemistry , kinetics , organic chemistry , quantum mechanics , computer science , programming language , catalysis

A discharge fast flow system with mass spectrometric detection was used to determine the rate constant of the title reaction to be k(1) = (1.3±0.2)×10 −13 cm 3 molecule −1 s −1 . This experimental value is roughly a factor of 20 higher than previously recommended. It is suggested that the title reaction should be considered as a removal process in modeling stratospheric HOCl.

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