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In situ measurements of midlatitude ClO in winter
Author(s) -
Toohey D. W.,
Brune W. H.,
Chan K. R.,
Anderson J. G.
Publication year - 1991
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1029/90gl02673
Subject(s) - middle latitudes , stratosphere , polar vortex , mixing ratio , ozone , atmospheric sciences , ozone depletion , northern hemisphere , southern hemisphere , atmospheric chemistry , environmental science , latitude , chlorine , climatology , vortex , in situ , chlorofluorocarbon , meteorology , chemistry , geology , physics , geodesy , organic chemistry
In situ measurements of ClO in the winter lower stratosphere are presented for six flights of the NASA ER‐2 aircraft from 38°N to 61°N. Enhanced abundances, increasing in severity with date, were observed below 20 km, where HCl and ClONO 2 dominate the inorganic chlorine budget. The greatest mixing ratios, over 150 pptv, were encountered on February 20 and 21, 1989, as the vortex experienced a major warming. Although the timing of these ClO enhancements and the evidence that vortex air can reach midlatitudes suggest that heterogeneous conversion of chlorine compounds within the vortex influences chemistry at midlatitudes, the enhancements observed early in the winter could have been caused by unknown chemistry occurring outside the vortex. In either case, photochemical loss of ozone due to catalytic reactions involving ClO at these mixing ratios may be responsible in part for the ozone decreases observed at high latitudes in the northern hemisphere.