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Ocean Dust Deposition Rates Constrained in a Data‐Assimilation Model of the Marine Aluminum Cycle
Author(s) -
Xu Hairong,
Weber Thomas
Publication year - 2021
Publication title -
global biogeochemical cycles
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.512
H-Index - 187
eISSN - 1944-9224
pISSN - 0886-6236
DOI - 10.1029/2021gb007049
Subject(s) - geotraces , aeolian processes , scavenging , geochemical cycle , deposition (geology) , environmental science , aerosol , mineral dust , oceanography , atmospheric sciences , iron fertilization , hydrothermal vent , dimethyl sulfide , water column , biogeochemistry , transect , environmental chemistry , geology , phytoplankton , hydrothermal circulation , sediment , chemistry , nutrient , paleontology , biochemistry , sulfur , organic chemistry , geomorphology , seismology , antioxidant
Aluminum (Al) is delivered to surface ocean waters by aeolian dust, making it a promising tracer to constrain dust deposition rates and the atmospheric supply of trace metal micronutrients. Over recent years, dissolved Al has been mapped along the GEOTRACES transects, providing unparalleled coverage of the world ocean. However, inferring atmospheric input rates from these observations is complicated by a suite of additional processes that influence the Al distribution, including reversible particle scavenging, biological uptake by diatoms, hydrothermal sources, sediment resuspension. Here we employ a data‐assimilation model of the oceanic Al cycle that explicitly accounts for these processes, allowing the atmospheric signal to be extracted. We conduct an ensemble of model optimizations that test different dust deposition distributions and consider spatial variations in Al solubility, thereby inferring the atmospheric Al supply that is most consistent with GEOTRACES observations. We find that 37.2 ± 11.0 Gmol/yr of soluble Al is added to the global ocean, dominated in the Atlantic Ocean, and that Al fractional solubility varies strongly as a function of atmospheric dust concentration. Our model also suggests that 6.1 ± 2.4 Gmol Al/yr is injected from hydrothermal vents, and that vertical Al redistribution through the water column is dominated by abiotic reversible scavenging rather than uptake by diatoms. Our results have important implications for the oceanic iron (Fe) budget: based on the soluble Fe:Al ratio of dust, we infer that aeolian Fe inputs lie between 3.82 and 9.25 Gmol/yr globally, and fall short of the biological Fe demand in most ocean regions.