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Revising the Ozone Depletion Potentials Metric for Short‐Lived Chemicals Such as CF 3 I and CH 3 I
Author(s) -
Zhang Jun,
Wuebbles Donald J.,
Kinnison Douglas E.,
SaizLopez Alfonso
Publication year - 2020
Publication title -
journal of geophysical research: atmospheres
Language(s) - English
Resource type - Journals
eISSN - 2169-8996
pISSN - 2169-897X
DOI - 10.1029/2020jd032414
Subject(s) - stratosphere , ozone , ozone layer , ozone depletion , atmospheric sciences , tonne , environmental science , troposphere , atmospheric chemistry , tropospheric ozone , chemistry , geology , organic chemistry
Ozone depletion potentials (ODPs) are an important metric in national and international policy for evaluating the relative importance of different gases to affecting stratospheric ozone. In evaluating the ODPs of iodotrifluoromethane (CF 3 I) and methyl iodide (CH 3 I) using the recently updated understanding of atmospheric iodine chemistry, only minor ozone loss would be expected to occur in the stratosphere from the very short‐lived (~6 days) CF 3 I, with slightly larger destruction of stratospheric ozone from CH 3 I (~12 days). In addition, most of the ozone destruction would likely occur in the lower troposphere over continental surfaces, reducing anthropogenic ozone pollution. The traditional ODP concept uses total column ozone change, but this is not an accurate representation of potential future use of very short‐lived substances (VSLSs) on the abundance of stratospheric ozone. A new metric, Stratospheric ODP (or SODP), is defined that only accounts for stratospheric ozone loss, providing a useful additional tool for policy considerations of VSLSs on stratospheric ozone.