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Strong Sequestration of Hydrogen Into the Earth's Core During Planetary Differentiation
Author(s) -
Yuan Liang,
SteinleNeumann Gerd
Publication year - 2020
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1029/2020gl088303
Subject(s) - silicate , hydrogen , mantle (geology) , earth (classical element) , metal , silicon , post perovskite , phase (matter) , magnesium , alkaline earth metal , astrobiology , geology , materials science , chemical physics , mineralogy , chemistry , geochemistry , physics , metallurgy , organic chemistry , mathematical physics
We explore the partitioning behavior of hydrogen between coexisting metal and silicate melts at conditions of the magma ocean and the current core–mantle boundary with the help of density functional theory molecular dynamics. We perform simulations with the two‐phase and thermodynamic integration methods. We find that hydrogen is weakly siderophile at low pressure (20 GPa and 2,500 K), and becomes much more strongly so with pressure, suggesting that hydrogen is transported to the core in a significant amount during core segregation and is stable there. Based on our results, the core likely contains ~1 wt% H, assuming single‐stage formation and equilibration at 40 GPa. Our two‐phase simulations further suggest that silicon is entrained in the core‐forming metal, while magnesium remains in the silicate phase. This preferred incorporation of silicon hints at an explanation for the elevated Mg/Si ratio of the bulk silicate Earth relative to chondritic compositions.