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Cross Sections and Rate Coefficients for O + Reacting With N 2 , O 2 , and NO
Author(s) -
Viehland Larry A.,
Johnsen Rainer
Publication year - 2019
Publication title -
journal of geophysical research: atmospheres
Language(s) - English
Resource type - Journals
eISSN - 2169-8996
pISSN - 2169-897X
DOI - 10.1029/2019jd031186
Subject(s) - ion , skewness , atomic physics , field (mathematics) , perpendicular , distribution function , computational physics , anisotropy , boltzmann equation , kurtosis , physics , chemistry , geometry , mathematics , optics , quantum mechanics , statistics , pure mathematics
Ion‐molecule reaction cross sections between 0.03 and 3 eV can best be inferred from data taken in drift tube mass spectrometers. For the title reactions, the cross sections inferred from drift‐tube measurements in the late 1970s have been accepted as accurate, even though the methods used to infer them made substantial assumptions about the ion velocity distribution functions. Here the Gram‐Charlier method for solving the Boltzmann equation is used to obtain ion distribution functions that are anisotropic, having different average energies parallel and perpendicular to the uniform electrostatic field. The Gram‐Charlier method incorporates skewness, kurtosis, and correlation between the motions parallel and perpendicular to the field. This leads to more accurate ion distribution functions from which more accurate reaction cross sections have been inferred. The results differ by as much as 50% from the generally accepted cross sections that are currently used to model ion‐neutral reactions in the upper atmosphere.