Open AccessThe Climatic Effects of Hygroscopic Growth of Sulfate Aerosols in the Stratosphere
Author(s) -
Krishnamohan K.S.,
Bala Govindasamy,
Cao Long,
Duan Lei,
Caldeira Ken
Publication year - 2020
Publication title -
earth's future
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.641
H-Index - 39
ISSN - 2328-4277
DOI - 10.1029/2019ef001326
Subject(s) - stratosphere , sulfate aerosol , aerosol , atmospheric sciences , relative humidity , sulfate , environmental science , water vapor , climatology , meteorology , chemistry , geography , physics , geology , organic chemistry
Solar geoengineering by deliberate injection of sulfate aerosols in the stratosphere is one of the proposed options to counter anthropogenic climate warming. In this study, we focus on the effect of a specific microphysical property of sulfate aerosols in the stratosphere: hygroscopic growth—the tendency of particles to grow by accumulating water. We show that stratospheric sulfate aerosols, for a given mass of sulfates, cause more cooling when prescribed at the lower levels of the stratosphere because of hygroscopic growth. The larger relative humidity in the lower stratosphere causes an increase in the aerosol size through hygroscopic growth that leads to a larger scattering efficiency. In our study, hygroscopic growth provides an additional cooling of 23% (0.7 K) when 20 Mt‐SO 4 of sulfate aerosols, an amount that approximately offsets the warming due to a doubling of CO 2 , are prescribed at 100 hPa. The hygroscopic effect becomes weaker at higher levels as relative humidity decreases with height. Hygroscopic growth also leads to secondary effects such as an increase in near‐infrared shortwave absorption by the aerosols that causes a decrease in high clouds and an increase in stratospheric water vapor. The altitude dependence of the effects of hygroscopic growth is opposite to that of sedimentation effects or the fast adjustment effects due to aerosol‐induced warming identified in a recent study.