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Trends of Ocean Acidification and p CO 2 in the Northern North Sea, 2003–2015
Author(s) -
Omar A. M.,
Thomas H.,
Olsen A.,
Becker M.,
Skjelvan I.,
Reverdin G.
Publication year - 2019
Publication title -
journal of geophysical research: biogeosciences
Language(s) - English
Resource type - Journals
eISSN - 2169-8961
pISSN - 2169-8953
DOI - 10.1029/2018jg004992
Subject(s) - alkalinity , oceanography , seawater , ocean acidification , environmental science , carbon dioxide , aragonite , dissolved organic carbon , total inorganic carbon , sea surface temperature , climatology , geology , chemistry , mineralogy , organic chemistry , calcite
For continental shelf regions, the long‐term trend in sea surface carbon dioxide (CO 2 ) partial pressure ( p CO 2 ) and rates of ocean acidification are not accurately known. Here, we investigate the decadal trend of observed wintertime p CO 2 as well as computed wintertime pH and aragonite saturation state (Ω ar ) in the northern North Sea, using the first decade long monthly underway data from a voluntary observing ship covering the period 2004–2015. We also evaluate how seawater CO 2 chemistry, in response to physical and biological processes, drives variations in the above parameters on seasonal and interannual timescales. In the northern North Sea, p CO 2 , pH, and Ω ar are subject to strong seasonal variations with mean wintertime values of 375 ± 11 μatm, 8.17 ± 0.01, and 1.96 ± 0.05. Dissolved inorganic carbon is found to be the primary driver of both seasonal and interannual changes while total alkalinity and sea surface temperature have secondary effects that reduce the changes produced by dissolved inorganic carbon. Average interannual variations during winter are around 3%, 0.1%, and 2% for p CO 2 , pH, and Ω ar , respectively and slightly larger in the eastern part of the study area (Skagerrak region) than in the western part (North Atlantic Water region). Statistically significant long‐term trends were found only in the North Atlantic Water region with mean annual rates of 2.39 ± 0.58 μatm/year, −0.0024 ± 0.001 year ‐1 , and −0.010 ± 0.003 year ‐1 for p CO 2 , pH, and Ω ar , respectively. The drivers of the observed trends as well as reasons for the lack of statistically significant trends in the Skagerrak region are discussed.