Open AccessPyrolytic Gaseous Hydrocarbon Generation and the Kinetics of Carbon Isotope Fractionation in Representative Model Compounds With Different Chemical Structures
Author(s) -
Lu Shuangfang,
Li Jijun,
Xue Haitao,
Chen Fangwen,
Xu Qingxia,
Wang Min,
Li Wenbiao,
Pang Xiaoting
Publication year - 2019
Publication title -
geochemistry, geophysics, geosystems
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.928
H-Index - 136
ISSN - 1525-2027
DOI - 10.1029/2018gc007722
Subject(s) - fractionation , equilibrium fractionation , methane , isotopes of carbon , carbon fibers , hydrocarbon , pyrolysis , isotope fractionation , pyrolytic carbon , gas composition , natural gas , stable isotope ratio , chemistry , environmental chemistry , organic chemistry , materials science , thermodynamics , total organic carbon , physics , quantum mechanics , composite number , composite material
Five model compounds with representative chemical structures were selected for use in simulation experiments of pyrolytic gas production. The gas production and isotopic fractionation characteristics were observed and analyzed. Then, the factors affecting carbon isotope fractionation during natural gas generation were discussed, and a fractionation model was established and calibrated. We concluded that the final hydrocarbon gas (C 1–5 ) yield of octadecane, octadecylamine, octadecanoic acid, decahydronaphthalene, and 9‐phenylanthracene decreased in turn with the effective hydrogen content. Compared with linear alkanes or alkyl compounds, cycloalkanes have higher thermal stability and generate gas later. The variation in the carbon isotopic composition of natural gas is primarily controlled by the following three factors: (a) the thermal evolution of organic matter results in a gradually heavier isotopic composition for the main gas production stage. (b) Gas inherits the isotopic composition of its parent material, and this effect is evident when the chemical structure and gas generation mechanism between parent materials are similar. (c) The structure of organic matter determines the reaction mechanism of gas generation, which has a significant influence on the range and trend of carbon isotope fractionation in the process of methane generation. An improved chemical kinetic model can accurately characterize carbon isotope fractionation during gas generation.