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Environmental Controls on the Riverine Export of Dissolved Black Carbon
Author(s) -
Jones Matthew W.,
Aragão Luiz E. O. C.,
Dittmar Thorsten,
Rezende Carlos E.,
Almeida Marcelo G.,
Johnson Ben T.,
Marques Jomar S. J.,
Niggemann Jutta,
Rangel Thiago P.,
Quine Timothy A.
Publication year - 2019
Publication title -
global biogeochemical cycles
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.512
H-Index - 187
eISSN - 1944-9224
pISSN - 0886-6236
DOI - 10.1029/2018gb006140
Subject(s) - terrigenous sediment , environmental science , dissolved organic carbon , carbon cycle , sink (geography) , charcoal , drainage basin , carbon sink , hydrology (agriculture) , dbc , total organic carbon , environmental chemistry , climate change , geology , sediment , oceanography , chemistry , ecology , ecosystem , geomorphology , physics , cartography , geotechnical engineering , organic chemistry , phase noise , geography , optics , biology
Each year, tropical rivers export a dissolved organic carbon (DOC) flux to the global oceans that is equivalent to ~4% of the global land sink for atmospheric CO 2 . Among the most refractory fractions of terrigenous DOC is dissolved black carbon (DBC), which constitutes ~10% of the total DOC flux and derives from the charcoal and soot (aerosol) produced during biomass burning and fossil fuel combustion. Black carbon (BC) has disproportionate storage potential in oceanic pools and so its export has implications for the fate and residence time of terrigenous organic carbon (OC). In contrast to bulk DOC, there is limited knowledge of the environmental factors that control riverine fluxes of DBC. We thus completed a comprehensive assessment of the factors controlling DBC export in tropical rivers with catchments distributed across environmental gradients of hydrology, topography, climate, and soil properties. Generalized linear models explained 70 and 64% of the observed variance in DOC and DBC concentrations, respectively. DOC and DBC concentrations displayed coupled responses to the dominant factors controlling their riverine export (soil moisture, catchment slope, and catchment stocks of OC or BC, respectively) but varied divergently across gradients of temperature and soil properties. DBC concentrations also varied strongly with aerosol BC deposition rate, indicating further potential for deviation of DBC fluxes from those of DOC due to secondary inputs of DBC from this unmatched source. Overall, this study identifies the specific drivers of BC dynamics in river catchments and fundamentally enhances our understanding of refractory DOC export to the global oceans.