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Water interactions with micronized lunar surrogates JSC‐1A and albite under ultra‐high vacuum with application to lunar observations
Author(s) -
Poston Michael J.,
Grieves Gregory A.,
Aleksandrov Alexandr B.,
Hibbitts Charles A.,
Darby Dyar M.,
Orlando Thomas M.
Publication year - 2013
Publication title -
journal of geophysical research: planets
Language(s) - English
Resource type - Journals
eISSN - 2169-9100
pISSN - 2169-9097
DOI - 10.1029/2012je004283
Subject(s) - albite , desorption , diffuse reflectance infrared fourier transform , regolith , analytical chemistry (journal) , chemistry , chemisorption , fourier transform infrared spectroscopy , attenuated total reflection , thermal desorption , infrared spectroscopy , mineralogy , adsorption , materials science , chemical engineering , environmental chemistry , astrobiology , organic chemistry , catalysis , quartz , physics , photocatalysis , engineering , composite material
Interactions of molecular water with two lunar regolith surrogates (micronized JSC‐1A and albite) were examined using temperature program desorption (TPD) and diffuse reflectance infrared Fourier transform spectroscopy. TPD revealed water desorption during initial heating to 750 K under ultrahigh vacuum and diffuse reflectance infrared Fourier transform spectroscopy indicated possible water formation via recombinative desorption of native hydroxyls above 425 ± 25 K. Dissociative chemisorption of water (i.e., formation of surface hydroxyl sites) was not observed on laboratory time scales after controlled dosing of samples (initially heated above 750 K) with 0.2–500 L exposures of water. However, preheated samples of both types of surrogates were found to have a distribution of molecular water chemisorption sites, with albite having at least twice as many as the JSC‐1A samples by mass. A fit to the TPD data yields a distribution function of desorption activation energies ranging from ~ 0.45 to 1.2 eV. Using the fitted distribution function as an initial condition, the TPD process was simulated on the time scale of a lunation.