
Sea surface p CO 2 cycles and CO 2 fluxes at landfast sea ice edges in Amundsen Gulf, Canada
Author(s) -
Else B. G. T.,
Galley R. J.,
Papakyriakou T. N.,
Miller L. A.,
Mucci A.,
Barber D.
Publication year - 2012
Publication title -
journal of geophysical research: oceans
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.67
H-Index - 298
eISSN - 2156-2202
pISSN - 0148-0227
DOI - 10.1029/2012jc007901
Subject(s) - upwelling , sea ice , geology , oceanography , ice shelf , arctic ice pack , environmental science , atmospheric sciences , cryosphere , climatology
In late fall, spring, and early summer, we measured the surface ocean and atmospheric partial pressures of CO 2 ( p CO 2 sw and p CO 2 atm , respectively) to calculate CO 2 gradients (Δ p CO 2 = p CO 2 sw − p CO 2 atm ) and resulting fluxes along the landfast ice regions of southern Amundsen Gulf, Canada. In both the fall and spring seasons we observed positive Δ p CO 2 caused by wind‐driven upwelling. The presence of a landfast ice edge appeared to be an important factor in promoting this upwelling in some instances. Despite the potential for significant CO 2 evasion, we calculated small fluxes during these periods due to high sea ice concentration. In summer, Δ p CO 2 became strongly negative across the entire study area. Primary production no doubt played a role in the p CO 2 sw drawdown, but we found evidence that sea ice melt and dissolution of ice‐bound calcium carbonate crystals may also have been contributing factors. The seasonal Δ p CO 2 cycle suggests a net annual sink of atmospheric CO 2 for these landfast ice regions, since calculated summer uptake by the ocean was much stronger than fall/spring outgassing and occurred over a longer time period. However, we hypothesize that this balance is highly dependent on the strength of upwelling and the timing of ice formation and decay, and therefore may be influenced by interannual variability and the effects of climate change.