Open AccessU/Ca in benthic foraminifers: A proxy for the deep‐sea carbonate saturation
Author(s) -
Raitzsch Markus,
Kuhnert Henning,
Hathorne Ed C.,
Groeneveld Jeroen,
Bickert Torsten
Publication year - 2011
Publication title -
geochemistry, geophysics, geosystems
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.928
H-Index - 136
ISSN - 1525-2027
DOI - 10.1029/2010gc003344
Subject(s) - foraminifera , benthic zone , geology , carbonate , oceanography , calcite , saturation (graph theory) , seawater , deep sea , plankton , calcium carbonate , paleontology , chemistry , mathematics , organic chemistry , combinatorics
The ocean plays a major role in the global carbon cycle, and attempts to reconstruct past changes in the marine carbonate system are increasing. The speciation of dissolved uranium is sensitive to variations in carbonate system parameters, and previous studies have shown that this is recorded in the uranium‐to‐calcium ratio (U/Ca) of the calcite shells of planktonic foraminifera. Here we test whether U/Ca ratios of deep‐sea benthic foraminifera are equally suited as an indicator of the carbonate system. We compare U/Ca in two common benthic foraminifer species ( Planulina wuellerstorfi and Cibicidoides mundulus ) from South Atlantic core top samples with the calcite saturation state (Δ[CO 3 2− ] = [CO 3 2− ] in situ − [CO 3 2− ] sat ) of the ambient seawater and find significant negative correlations for both species. Compared with planktonic foraminifera, the sensitivity of U/Ca in benthic foraminifera to changes in Δ[CO 3 2− ] is about 1 order of magnitude higher. Although Δ[CO 3 2− ] exerts the dominant control on the average foraminiferal U/Ca, the intertest and intratest variability indicates the presence of additional factors forcing U/Ca.