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Water‐CO 2 ‐mineral systems: Interfacial tension, contact angle, and diffusion—Implications to CO 2 geological storage
Author(s) -
Espinoza D. Nicolas,
Santamarina J. Carlos
Publication year - 2010
Publication title -
water resources research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.863
H-Index - 217
eISSN - 1944-7973
pISSN - 0043-1397
DOI - 10.1029/2009wr008634
Subject(s) - contact angle , surface tension , calcite , dissolution , quartz , diffusion , mineralogy , chemistry , wetting , materials science , chemical engineering , thermodynamics , composite material , organic chemistry , physics , engineering
The interfacial interaction between mineral surfaces and immiscible fluids determines the efficiency of enhanced oil or gas recovery operations as well as our ability to inject and store CO 2 in geological formations. Previous studies have shown that the interfacial tension and contact angle in CO 2 ‐water‐mineral systems change noticeably with fluid pressure. We compile previous results and extend the scope of available data to include saline water, different substrates (quartz, calcite, oil‐wet quartz, and polytetrafluoroethylene (PTFE)), and a wide pressure range (up to 20 MPa at 298K). Data analysis provides interfacial tension and contact angle as a function of fluid pressure; in addition, we recover the diffusion coefficient of water in liquid CO 2 from long‐term observations. Results show that CO 2 ‐water interfacial tension decreases significantly as pressure increases in agreement with previous studies. Contact angle varies with CO 2 pressure in all experiments in response to changes in CO 2 ‐water interfacial tension: it increases on nonwetting surfaces such as PTFE and oil‐wet quartz and slightly decreases in water‐wet quartz and calcite surfaces. Water solubility and its high diffusivity ( D = 2 × 10 −8 to 2 × 10 −7 m 2 /s) in liquid CO 2 govern the evolution of interparticle pendular water. CO 2 ‐derived ionic species interaction with the substrate leads to surface modification if reactions are favorable, e.g., calcite dissolution by carbonic acid and precipitation as water diffuses and migrates into the bulk CO 2 . Pressure‐dependent interfacial tension and contact angle affect injection patterns and breakthrough mechanisms, in other words, the performance of geological formations that act as either reservoirs or seals.