Open AccessIsotopic constraints on alkalinity, dissolved organic carbon, and atmospheric carbon dioxide fluxes in the Mississippi River
Author(s) -
Dubois Kristal D.,
Lee Dongho,
Veizer Ján
Publication year - 2010
Publication title -
journal of geophysical research: biogeosciences
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.67
H-Index - 298
eISSN - 2156-2202
pISSN - 0148-0227
DOI - 10.1029/2009jg001102
Subject(s) - alkalinity , dissolved organic carbon , tributary , total inorganic carbon , carbon dioxide , carbon cycle , flux (metallurgy) , carbonate , carbon fibers , environmental science , environmental chemistry , isotopes of carbon , hydrology (agriculture) , total organic carbon , carbon dioxide in earth's atmosphere , geology , chemistry , ecology , ecosystem , materials science , cartography , geotechnical engineering , organic chemistry , composite number , composite material , biology , geography
We examined carbon cycling in the Mississippi River using stable isotopes of inorganic carbon and dissolved oxygen. Eighteen sites were sampled along the river and its tributaries over 1 year. We estimate using a conservative approach that the flux of CO 2 to the atmosphere (1 × 10 13 g C yr −1 ) approximately equaled the flux of alkalinity to the Gulf of Mexico (9.7 × 10 12 g C yr −1 ) and greatly exceeded the flux of dissolved organic carbon (1.5 × 10 12 g C yr −1 ). Though only a first‐order estimate, our work shows that the atmospheric flux of CO 2 is significant and should not be ignored when examining the carbon budget of the Mississippi River. As expected, because of the large area covered by the Mississippi watershed, the isotopic composition of dissolved inorganic carbon, δ 13 C DIC , varied widely. In the Ohio and upper and lower Mississippi basins, δ 13 C DIC indicates that the source of inorganic carbon in the rivers is primarily from carbonate dissolution by soil CO 2 . Dissolved inorganic carbon in the Missouri River was enriched in 13 C, and the isotopic composition of dissolved oxygen in this river suggests that this results from an excess of aquatic photosynthesis over respiration.