Open AccessThe use of PARAFAC modeling to trace terrestrial dissolved organic matter and fingerprint water masses in coastal Canadian Arctic surface waters
Author(s) -
Walker Sally A.,
Amon Rainer M. W.,
Stedmon Colin,
Duan Shuiwang,
Louchouarn Patrick
Publication year - 2009
Publication title -
journal of geophysical research: biogeosciences
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.67
H-Index - 298
eISSN - 2156-2202
pISSN - 0148-0227
DOI - 10.1029/2009jg000990
Subject(s) - colored dissolved organic matter , dissolved organic carbon , archipelago , environmental science , plume , oceanography , water mass , surface water , arctic , transect , seawater , salinity , organic matter , environmental chemistry , geology , ecology , chemistry , phytoplankton , physics , environmental engineering , nutrient , biology , thermodynamics
The optical properties of chromophoric dissolved organic matter (CDOM) were investigated in the Canadian Archipelago and coastal Beaufort Sea surface waters using fluorescence spectroscopy coupled with parallel factor analysis (PARAFAC). Environmental dynamics of individual components were evaluated and compared to salinity, in situ fluorescence, absorption at 312 nm ( a 312 ), dissolved organic carbon, and lignin phenol concentrations. A positive linear relationship between four fluorescent components and lignin phenols suggests a terrestrial origin, whereas two components were unrelated to a river source, suggesting an autochthonous source. Elevated concentrations of terrestrial components were observed in the Mackenzie River plume near the coast of Alaska and decreased as water was transported to the Canadian Archipelago. The two nonterrestrial components exhibited only background levels in concentrations along the transect, suggesting minimal productivity within plume and archipelago surface waters. The relative abundance of terrestrial components in relation to nonterrestrial components allowed us to distinguish water masses including Atlantic, Archipelago, and Mackenzie River plume, respectively. This study illustrates the usefulness of PARAFAC to fingerprint water masses based on the optical characteristics of CDOM and shows promise to improve our understanding of upper Arctic Ocean ventilation.