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Identification of a subduction zone component in the Higganum dike, Central Atlantic Magmatic Province: A LA‐ICPMS study of clinopyroxene with implications for flood basalt petrogenesis
Author(s) -
Dorais Michael J.,
Tubrett Michael
Publication year - 2008
Publication title -
geochemistry, geophysics, geosystems
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.928
H-Index - 136
ISSN - 1525-2027
DOI - 10.1029/2008gc002079
Subject(s) - geology , basalt , flood basalt , geochemistry , petrogenesis , mantle (geology) , phenocryst , subduction , incompatible element , trace element , primitive mantle , metasomatism , olivine , volcanic rock , volcano , partial melting , paleontology , tectonics , volcanism
Determining the primary compositions of continental flood basalts has proven allusive because of the masking effects of crustal contamination. The Higganum dike (Connecticut, USA) that fed the Talcott basalt of the Central Atlantic Magmatic Province hosts strongly zoned clinopyroxenes. The cores are Mg‐ and Cr‐rich, containing up to 1 wt % Cr 2 O 3 . The grains show optical and major, minor, and trace element continua between cores and their mantles and rims, indicating that the cores are early crystallizing phenocrysts, not xenocrysts. Laser ablation inductively coupled plasma mass spectrometry analyses of the cores were used to calculate liquid compositions of the most primitive component in the Higganum system and to make inferences about composition of continental flood basalt parental magmas. The Cr‐rich cores yield calculated liquids with Mg numbers of 63. The high‐Cr contents of these calculated liquids indicate the absence of significant clinoproxene or chromite fractionation. Olivine or orthopyroxene fractionation may have lowered the liquid Mg number but would not have significantly influenced the calculated incompatible trace element patterns. Extended rare earth element diagrams for the most Cr‐rich liquids show enrichment in incompatible elements, similar to arc basalts. Prominent negative Nb anomalies are present as are distinct positive Pb anomalies indicative of the influence of subduction zone fluids in the mantle source. Calculated liquid Ba/La values range from 3 to 30, also suggestive of fluid input. These data indicate that the mantle source experienced subduction zone fluid metasomatism. Subsequent crustal contamination is evident in bulk‐rock Nd and Sr isotopic compositions.

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