Open AccessConstraints on mantle source and interactions from He‐Sr isotope variation in Italian Plio‐Quaternary volcanism
Author(s) -
Martelli M.,
Nuccio P. M.,
Stuart F. M.,
Di Liberto V.,
Ellam R. M.
Publication year - 2008
Publication title -
geochemistry, geophysics, geosystems
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.928
H-Index - 136
ISSN - 1525-2027
DOI - 10.1029/2007gc001730
Subject(s) - geology , mantle (geology) , subduction , geochemistry , metasomatism , mantle wedge , phenocryst , basalt , radiogenic nuclide , pyroxene , volcanic rock , olivine , volcano , paleontology , tectonics
Helium isotope ratios of olivine and pyroxene phenocrysts from Plio‐Quaternary volcanic rocks from southern Italy (seven Aeolian Islands, Mt. Vulture, Etna, Ustica, and Pantelleria) range from 2.3 to 7.1 R a . Importantly, the phenocryst 3 He/ 4 He correlate well with whole rock Sr isotopic composition (0.70309–0.70711), reflecting the mixing of two sources. A significant contribution of He from crustal contamination is recorded only occasionally (e.g., pyroxenes from Vulcano). When merged with data from the Roman Comagmatic Province, a remarkably strong near‐linear He‐Sr isotope correlation is apparent. The general northward decrease in 3 He/ 4 He corresponds to an increase in 87 Sr/ 86 Sr (and a decrease in 143 Nd/ 144 Nd and 206 Pb/ 204 Pb) that is due to increasing metasomatic enrichment of the mantle wedge via subduction of the Ionian‐Adriatic plate. Calculations based on the ingrowth of 4 He in the wedge and on the 4 He content of the subducting crust show that mechanisms of enrichment in radiogenic He are effective only if the wedge is strongly depleted in He relative to best estimates of the depleted mantle. This can be accommodated if the process of metasomatism by the subduction fluids depletes the mantle wedge. The 3 He/ 4 He of Pantelleria, Etna, Iblei, Ustica, Alicudi, and Filicudi basalts (7.0 ± 0.6 R a ) define the mantle composition least affected by subduction‐related metasomatism. Although these volcanoes are from a variety of tectonic regimes (subduction‐related, intraplate, rifting), their similarities suggest a common origin of geochemical features. Their characteristics are consistent with a HIMU‐type mantle that either is younger than the Cook‐Austral island end‐member or has a lower 238 U/ 204 Pb.