Open AccessParameterization for the relative humidity dependence of light extinction: Organic‐ammonium sulfate aerosol
Author(s) -
Garland Rebecca M.,
Ravishankara A. R.,
Lovejoy Edward R.,
Tolbert Margaret A.,
Baynard Tahllee
Publication year - 2007
Publication title -
journal of geophysical research: atmospheres
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.67
H-Index - 298
eISSN - 2156-2202
pISSN - 0148-0227
DOI - 10.1029/2006jd008179
Subject(s) - aerosol , ammonium sulfate , relative humidity , sulfate , chemistry , molar absorptivity , particle (ecology) , ammonium , particle size , humidity , environmental chemistry , extinction (optical mineralogy) , fraction (chemistry) , chemical composition , mineralogy , organic chemistry , meteorology , physics , oceanography , optics , geology
Atmospheric particles are a complex mixture of inorganic and organic compounds. This study uses laboratory generated particles to examine the connection between aerosol light extinction, chemical composition, and hygroscopicity for particles composed of internal mixtures of ammonium sulfate and water‐soluble organic compounds. The extinction coefficient ( σ ep ) at 532 nm was measured for size‐selected particles at <10% RH and 80% RH. The ratio of the extinction coefficients at 80% RH to <10% RH is reported as fRH ext (80% RH, dry). The fRH ext (80% RH, dry) values were similar for particles composed of various water‐soluble organic compounds and different functional groups. In addition, fRH ext (80% RH, dry) values were relatively insensitive to the composition of the organic fraction for internal mixtures of ammonium sulfate with sugars, dicarboxylic acids and complex mixtures of water‐soluble organic compounds. Finally, fRH ext (80% RH, dry) was found to vary linearly with the organic/inorganic content, allowing for simple incorporation of organic properties into atmospheric models. We derived a generalization of fRH ext (80% RH, dry) = 2.90 – 0.015(wt% organic species) for a particle size distribution with a dry mean optical diameter of 0.35 μ m. This parameterization for ammonium sulfate/water‐soluble organic aerosol is applicable to the fine particle mode fraction of atmospheric aerosol. Information necessary to incorporate the variation in the size distribution is also included. This work suggests that neglecting the water uptake by the organic fraction of atmospheric particles could lead to significant underestimation of the cooling at the Earth's surface due to light scattering by aerosol.