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Nuclear resonant x‐ray scattering of iron hydride at high pressure
Author(s) -
Mao Wendy L.,
Sturhahn Wolfgang,
Heinz Dion L.,
Mao HoKwang,
Shu Jinfu,
Hemley Russell J.
Publication year - 2004
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1029/2004gl020541
Subject(s) - hydride , scattering , high pressure , materials science , nuclear physics , physics , optics , metallurgy , mechanics , metal
We studied the nuclear resonant x‐ray scattering of iron hydride (FeH x ) up to 52 GPa. Coupled with hydrostatic x‐ray diffraction data, the partial phonon density of states measured by nuclear resonant inelastic x‐ray scattering provides information on sound velocities and the Fe contribution to thermodynamic parameters. In particular it constrains the aggregate shear velocity and shear modulus for comparison to seismic observations. We found that V S (km/sec) = 0.023* P (GPa) + 3.2. A loss of magnetism was observed with synchrotron Mössbauer spectroscopy at 22 GPa, lower than theoretically predicted but consistent with the observed anomalous velocity behavior. Results confirm that FeH x could be a major light element bearing phase for explaining the core density deficit relative to pure Fe. Formation of FeH x by reaction with water would be expected to leave a signature in the mantle.