
Neodymium isotopic composition and rare earth element concentrations in the deep and intermediate Nordic Seas: Constraints on the Iceland Scotland Overflow Water signature
Author(s) -
Lacan François,
Jeandel Catherine
Publication year - 2004
Publication title -
geochemistry, geophysics, geosystems
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.928
H-Index - 136
ISSN - 1525-2027
DOI - 10.1029/2004gc000742
Subject(s) - radiogenic nuclide , neodymium , geology , seawater , isotopic signature , geochemistry , geotraces , rare earth element , water mass , basalt , oceanography , trace element , isotope , rare earth , mineralogy , mantle (geology) , laser , physics , optics , quantum mechanics
Neodymium isotopic composition and rare earth element concentrations were measured in seawater samples from eleven stations in the Nordic Seas. These data allow us to study how the Iceland Scotland Overflow Water (ISOW) acquires its neodymium signature in the modern ocean. The waters overflowing the Faroe Shetland channel are characterized by ɛ Nd = −8.2 ± 0.6, in good agreement with the only other data point, published 19 years ago. In the Greenland and Iceland Seas the water masses leading to the formation of the ISOW display lower neodymium isotopic composition, with ɛ Nd around −11 and −9, respectively. Since no water masses in the Nordic Seas are characterized by ɛ Nd > −8, the radiogenic signature of the ISOW likely reflects inputs from the highly radiogenic Norwegian Basin basaltic margins (Jan‐Mayen, Iceland, Faroe, with ɛ Nd ≈ +7). In addition to the neodymium isotopic composition, the rare earth element patterns suggest that these inputs occur via the remobilization (which includes resuspension and dissolution) of sediments deposited on the margins. Whereas the neodymium isotopic composition behaves conservatively in the oceans in the absence of lithogenic inputs, and can be used as a water mass tracer, these results emphasize the role of interactions, between sediments deposited on margins and seawater, in the acquisition of the neodymium isotopic composition of water masses. These results should allow a better use of this parameter to trace the present and the past circulation in the North Atlantic.