Open AccessCrystallinity of foraminifera shells: A proxy to reconstruct past bottom water CO 3 = changes?
Author(s) -
Bassinot Franck C.,
Mélières Frédéric,
Gehlen Marion,
Levi Camille,
Labeyrie Laurent
Publication year - 2004
Publication title -
geochemistry, geophysics, geosystems
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.928
H-Index - 136
ISSN - 1525-2027
DOI - 10.1029/2003gc000668
Subject(s) - calcite , foraminifera , geology , globigerinoides , transect , carbonate , crystallinity , bottom water , last glacial maximum , oceanography , globigerina bulloides , mineralogy , geochemistry , paleontology , holocene , chemistry , organic chemistry , crystallography , benthic zone
The reconstruction of past changes in bottom water CO 3 = is central to evaluating competing oceanic scenarios that deal with long‐term variations in atmospheric pCO 2 . In search of a quantitative bottom water CO 3 = proxy, we analyzed the variations of calcite crystallinity of planktonic foraminifera Globigerinoides ruber shells picked from core top samples along three depth transects: Ontong Java Plateau and the northeast margin of Irian Jaya, in the western equatorial Pacific, and the Sierra Leone Rise, in the eastern tropical Atlantic. The strong empirical relationship between calcite crystallinity (inferred from the full width at half maximum (FWHM) of calcite (104) X‐ray diffraction peak) and bottom water saturation relative to calcite (ΔCO 3 ) shows that foraminifera calcite crystallinity could be a promising proxy for the reconstruction of upper Pleistocene bottom water carbonate ion concentration.