Open AccessRelaxed eddy accumulation measurements of the sea‐to‐air transfer of dimethylsulfide over the northeastern Pacific
Author(s) -
Zemmelink Hendrik J.,
Gieskes Winfried W. C.,
Klaassen Wim,
Beukema Wim J.,
de Groot Henk W.,
de Baar Hein J. W.,
Hintsa Eric J.,
McGillis Wade R.,
Dacey John W. H.
Publication year - 2004
Publication title -
journal of geophysical research: oceans
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.67
H-Index - 298
eISSN - 2156-2202
pISSN - 0148-0227
DOI - 10.1029/2002jc001616
Subject(s) - wind speed , environmental science , flux (metallurgy) , atmospheric sciences , meteorology , climatology , geology , chemistry , physics , organic chemistry
Gas transfer rates were determined from relaxed eddy accumulation (REA) measurements of the flux of dimethylsulfide (DMS) over the northeastern Pacific Ocean. This first application of the REA technique for the measurement of DMS fluxes over the open ocean produced estimates of the gas transfer rate that are on average higher than those calculated from commonly used parameterizations. The relationship between the total gas transfer rate and wind speed was found to be gas k gas = 0.53 (±0.05) U 10 2 . Because of the effect of the airside resistance, the waterside transfer rate was up to 16% higher than k gas . Removal of the airside transfer component from the total transfer rate resulted in a relation between wind speed and waterside transfer of k 660 = 0.61 (±0.06) U 10 2 . However, DMS fluxes showed a high degree of scatter that could not readily be accounted for by wind speed and atmospheric stability. It has to be concluded that these measurements do not permit an accurate parameterization of gas transfer as a function of wind speed.