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Direct shock wave loading of Stishovite to 235 GPa: Implications for perovskite stability relative to an oxide assemblage at lower mantle conditions
Author(s) -
Luo ShengNian,
Mosenfelder J. L.,
Asimow P. D.,
Ahrens Thomas J.
Publication year - 2002
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1029/2002gl015627
Subject(s) - stishovite , coesite , periclase , silicate perovskite , bulk modulus , equation of state , perovskite (structure) , thermodynamics , mineralogy , materials science , shock wave , mantle (geology) , grüneisen parameter , geology , quartz , chemistry , crystallography , geophysics , composite material , physics , eclogite , metallurgy , paleontology , thermal , subduction , magnesium , tectonics
Pure stishovite and coesite samples with zero porosity and dimensions appropriate for planar shock wave experiments have been synthesized with multi‐anvil high‐pressure techniques. The equation of state of stishovite is obtained by direct shock wave loading up to 235 GPa: K 0 T = 306 ± 5 GPa and K 0 T ′ = 5.0 ± 0.2 where K 0 T and K 0 T ′ are ambient bulk modulus and its pressure derivative, respectively. The Hugoniots (shock equations of state) for stishovite, coesite and quartz achieve widely differing internal energy states at equal volume and therefore allow us to determine the Gruneisen parameter of stishovite. On the basis of the resulting P ‐ V ‐ T equation of state for stishovite and previous studies on other phases on the MgO‐SiO 2 binary, the breakdown reaction of MgSiO 3 ‐perovskite to MgO and SiO 2 was calculated. Our calculations show that perovskite is thermodynamically stable relative to the stishovite and periclase assemblage at lower mantle conditions. We obtain similar results for a range of models, despite the appreciable differences among these experiment‐based thermodynamic parameters.