Open AccessMeasurement of silicon stable isotope natural abundances via multicollector inductively coupled plasma mass spectrometry (MC‐ICP‐MS)
Author(s) -
De La Rocha Christina L.
Publication year - 2002
Publication title -
geochemistry, geophysics, geosystems
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.928
H-Index - 136
ISSN - 1525-2027
DOI - 10.1029/2002gc000310
Subject(s) - isotopes of silicon , inductively coupled plasma mass spectrometry , isotope , silicon , mass spectrometry , analytical chemistry (journal) , inductively coupled plasma , stable isotope ratio , isotope ratio mass spectrometry , tracer , isotope analysis , geology , environmental chemistry , plasma , materials science , chemistry , oceanography , chromatography , physics , nuclear physics , metallurgy
Widespread utilization of silicon isotope ratio variations (δ 29 Si and δ 30 Si) as a geochemical and paleoceanographic tracer has been hampered by the hazardous nature of the analysis, which requires the use of a fluorinating gas. Multicollector inductively coupled plasma mass spectrometry (MC‐ICP‐MS) provides a safer means of silicon isotope analysis. High backgrounds, long rinsing and sample introduction times, and interferences are significant difficulties. It is possible to work around these obstacles, and the measurement of δ 29 Si may be done to a precision averaging ± 0.1‰. The δ 30 Si, which cannot be measured directly due to a NO interference at mass 30, may be extrapolated from the theoretically derived and empirically verified relationship, δ 30 Si = 1.93δ 29 Si. Biological materials (sponge spicules and diatoms) measured via MC‐ICP‐MS yielded δ 30 Si values in the ranges expected from the prior analysis of similar samples by the method of fluorination.