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Transport modeling applied to the interpretation of groundwater 36 Cl age
Author(s) -
Park Jungho,
Bethke Craig M.,
Torgersen Thomas,
Johnson Thomas M.
Publication year - 2002
Publication title -
water resources research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.863
H-Index - 217
eISSN - 1944-7973
pISSN - 0043-1397
DOI - 10.1029/2001wr000399
Subject(s) - aquifer , groundwater , groundwater flow , geology , diffusion , flow (mathematics) , isotope , hydrology (agriculture) , soil science , mechanics , thermodynamics , physics , geotechnical engineering , quantum mechanics
We use reactive transport modeling to consider how diffusion and hydrodynamic dispersion, cross‐formational flow, and subsurface production affect the steady state distribution in flow regimes of the radioactive isotope 36 Cl, and the relationship of the isotope distribution to groundwater residence time, or “age.” The isotope forms naturally in the atmosphere, dissolves in rainwater, and then decays in the subsurface with a half‐life of ∼301,000 years; hence it is important for age dating very old groundwater. In a simple flow regime composed of an aquifer confined above and below by aquitards, isotopic age may correspond rather well with a groundwater's “piston flow” age. This correspondence is favored where the aquifer is thick, cross‐formational flow is insignificant, salinity is low, and the diffusion coefficient within the aquitards is small. The maximum dateable age, however, is somewhat smaller than expected from the isotope's half‐life. Owing to the effect of “dead” chloride, dating based on isotope abundance (the 36 Cl/Cl ratio) may be less accurate than that based on 36 Cl concentration. Cross‐formational flow can strongly affect the 36 Cl distribution and abundance, preventing the rates and even direction of flow within an aquifer from being interpreted using the piston flow model. Where salinity is moderate or high, the isotope distribution is controlled by subsurface production, and dating on the basis of the decay of atmospheric 36 Cl is not possible. In models of simple flow regimes the 36 Cl method fails to predict groundwater age accurately where groundwater chlorinity exceeds ∼75–150 mg kg −1 . Reactive transport models hold considerable promise for improving interpretation of the rates and patterns of groundwater flow from radioisotope distributions.