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Stability and equation of state of Fe 3 C to 73 GPa: Implications for carbon in the Earth's core
Author(s) -
Scott Henry P.,
Williams Quentin,
Knittle Elise
Publication year - 2001
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1029/2000gl012606
Subject(s) - cementite , bulk modulus , compressibility , equation of state , materials science , inner core , thermodynamics , isothermal process , outer core , diffraction , diamond anvil cell , analytical chemistry (journal) , chemistry , high pressure , austenite , metallurgy , physics , microstructure , chromatography , optics , composite material
We have measured the volume and lattice parameters of Fe 3 C‐cementite as a function of pressure to 73 GPa using synchrotron‐based x‐ray diffraction. Several samples were laser heated and temperature‐quenched from >1,500 K while held at high‐pressure. No pressure or temperature induced phase transitions are observed in this study, and the 300 K isothermal equation of state of Fe 3 C yields a best‐fit bulk modulus, K 0 T , of 175±4 GPa and a of 5.2±0.3. The bulk sound speed of Fe 3 C under outer core conditions is calculated: barring higher pressure polymorphism or marked changes in compressibility on melting, carbon could produce some or all of the offset between seismic observations (PREM) and measurements on pure iron and iron‐nickel alloys. Additionally, we model the thermodynamic stability of this phase at the conditions of Earth's mantle, and determine that in the presence of free iron (i.e. during core formation) the formation of Fe 3 C is strongly favored relative to carbonates.