Open AccessA description of the global sulfur cycle and its controlling processes in the National Center for Atmospheric Research Community Climate Model, Version 3
Author(s) -
Rasch Philip J.,
Barth Mary C.,
Kiehl Jeffrey T.,
Schwartz Stephen E.,
Benkovitz Carmen M.
Publication year - 2000
Publication title -
journal of geophysical research: atmospheres
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.67
H-Index - 298
eISSN - 2156-2202
pISSN - 0148-0227
DOI - 10.1029/1999jd900777
Subject(s) - sulfate , aerosol , sulfur cycle , sulfate aerosol , atmospheric sciences , atmospheric chemistry , deposition (geology) , environmental science , atmosphere (unit) , atmospheric research , chemical transport model , climatology , meteorology , ozone , chemistry , geology , geography , paleontology , organic chemistry , sediment
We examine the balance between processes that contribute to the global and regional distributions of sulfate aerosol in the Earth's atmosphere using a set of simulations from the National Center for Atmospheric Research Community Climate Model, Version 3. The analysis suggests that the seasonal cycle of SO 2 and SO 4 2− are controlled by a complex interplay between transport, chemistry and deposition processes. The seasonal cycle of these species is not strongly controlled by temporal variations in emissions but by seasonal variations in volume of air processed by clouds, mass of liquid water serving as a site for aqueous chemistry, amount of oxidant available for the conversion from SO 2 to SO 4 2− , vertical transport processes, and deposition. A tagging of the sulfate by emission region (Europe, North America, Asia, and rest of world [ROW]), chemical pathway (gaseous versus in‐cloud), and type of emissions (anthropogenic versus biogenic) is used to differentiate the balance of processes controlling the production and loading from this material. Significant differences exist in the destiny of SO 2 molecules emitted from the several regions. An SO 2 molecule emitted from the ROW source region has a much greater potential to form sulfate than one emitted from, for example, Europe. A greater fraction of the SO 2 molecules is oxidized that originate from ROW compared with other areas, and once formed, the sulfate has a longer residence time (that is, it is not readily scavenged). The yield of sulfate from ROW sources of SO 2 is a factor of 4 higher than that of Europe. A substantially higher fraction of the SO 2 emitted over Europe is oxidized to sulfate through the ozone pathway compared to other regions. The analysis suggests that there are significant differences in the vertical distribution, and horizontal extent, of the propagation of sulfate emitted from the several source regions. Sulfate from Asian source regions reaches the farthest from its point of origin and makes a significant contribution to burdens in both hemispheres, primarily from plumes reaching out in the upper troposphere. Sulfate from other source regions tends to remain trapped in their hemisphere of origin.