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Comment on « Diffusion of HNO 3 in ice »
Author(s) -
Dominé Florent,
Thibert Emmanuel
Publication year - 1998
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1029/1998gl900156
Subject(s) - solubility , diffusion , contamination , environmental science , measure (data warehouse) , thermodynamics , meteorology , mineralogy , chemistry , physics , computer science , data mining , ecology , biology
Sommerfeld et al. (1998) (hereafter: SKL) attempted to measure HNO 3 diffusion in ice. Although they used HNO 3 partial pressures much higher than atmospheric, they encountered contamination problems, and conclude that they could not obtain meaningful values of the diffusion coefficient of HNO 3 in ice. In earlier measurements, we used a method having some similarities with theirs (Dominé and Thibert, 1995). SKL suggest that our data may have been affected by contamination. Here we examine their methods, find many differences with ours, and demonstrate that our data was not affected by contamination. We point out questionable choices in their experimental procedure, and in the earlier work of Diehl et al. (1995) and discuss the difference between their solubility data and ours. We propose changes to the procedure of SKL, so that an independent set of reliable data can be obtained on the diffusion and solubility of HNO 3 in ice.