Novel Olefin Metathesis Ruthenium Catalysts Bearing Backbone-Substituted Unsymmetrical NHC Ligands | Zendy

Veronica Paradiso | Zendy; V. Bertolasi | Zendy; Fabia Grisi | Zendy

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Novel Olefin Metathesis Ruthenium Catalysts Bearing Backbone-Substituted Unsymmetrical NHC Ligands

Author(s) -

Veronica Paradiso,

V. Bertolasi,

Fabia Grisi

Publication year - 2014

Publication title -

organometallics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.231

H-Index - 172

eISSN - 1520-6041

pISSN - 0276-7333

DOI - 10.1021/om500731k

Subject(s) - chemistry , carbene , olefin metathesis , ruthenium , catalysis , metathesis , olefin fiber , salt metathesis reaction , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , polymerization , polymer

Stable Ru-based catalysts containing unsym-\udmetrical N-heterocyclic carbene (NHC) ligands with phenyl\udsubstituents on the backbone in syn and anti stereochemical\udrelationships have been easily prepared and fully characterized.\udPreliminary investigation revealed that, depending on the\udbackbone conguration, the new Ru complexes displayed\uddierent catalytic behaviors in representative olen metathesis\udreactions

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