Synthesis and Structure of Bis(phenyltetramethylcyclopentadienyl)titanium(III) Hydride: First Monomeric Bis(cyclopentadienyl)titanium(III) Hydride | Zendy

Jeannette M. de Wolf | Zendy; Auke Meetsma | Zendy; Jan H. Teuben | Zendy

Open Access

Synthesis and Structure of Bis(phenyltetramethylcyclopentadienyl)titanium(III) Hydride: First Monomeric Bis(cyclopentadienyl)titanium(III) Hydride

Author(s) -

Jeannette M. de Wolf,

Auke Meetsma,

Jan H. Teuben

Publication year - 1995

Publication title -

organometallics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.231

H-Index - 172

eISSN - 1520-6041

pISSN - 0276-7333

DOI - 10.1021/om00012a005

Subject(s) - cyclopentadienyl complex , citation , hydride , titanium , information retrieval , monomer , computer science , chemistry , world wide web , library science , nanotechnology , materials science , metal , organic chemistry , polymer , catalysis

The first structurally characterized monomeric bis(cyclopentadienyl)titanium(III) hydride, (C(5)PhMe(4))(2)TiH (4), was synthesized by hydrogenolysis of (C(5)PhMe(4))(2)TiMe (5). Hydride 4 was found to be a monomeric bent sandwich by X-ray diffraction methods, and the pentamethylcyclopentadienyl analogue (C(5)Me(5))(2)TiH (3) is concluded to possess a similar molecular structure by comparison between the spectroscopic and reactivity data for 3 and 4

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