Air- and Water-Stable Catalysts for Hydroamination/Cyclization. Synthesis and Application of CCC−NHC Pincer Complexes of Rh and Ir | Zendy

Eike B. Bauer | Zendy; Senthil A. Gurusamy Thangavelu | Zendy; T. Keith Hollis | Zendy; Ramel J. Rubio | Zendy; Joon Cho | Zendy; G. Kuchenbeiser | Zendy; Theodore R. Helgert | Zendy; Christopher S. Letko | Zendy; Fook S. Tham | Zendy

Open Access

Air- and Water-Stable Catalysts for Hydroamination/Cyclization. Synthesis and Application of CCC−NHC Pincer Complexes of Rh and Ir

Author(s) -

Eike B. Bauer,

Senthil A. Gurusamy Thangavelu,

T. Keith Hollis,

Ramel J. Rubio,

Joon Cho,

G. Kuchenbeiser,

Theodore R. Helgert,

Christopher S. Letko,

Fook S. Tham

Publication year - 2008

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/ol8000766

Subject(s) - hydroamination , pincer movement , chemistry , transmetalation , catalysis , metalation , combinatorial chemistry , scope (computer science) , medicinal chemistry , organic chemistry , computer science , programming language

The scope of CCC-NHC pincer complex synthetic methodology by metalation/transmetalation has been extended to Ir. Structural characterization revealed that it is isomorphous with the Rh complex. Both Rh and Ir complexes are efficient catalysts for the hydroamination/cyclization of secondary amines in the presence of air and/or water.

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