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Nanopatterning of Fluorinated Graphene by Electron Beam Irradiation
Author(s) -
Freddie Withers,
Thomas H. Bointon,
Marc Dubois,
Saverio Russo,
Monica F. Craciun
Publication year - 2011
Publication title -
nano letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.853
H-Index - 488
eISSN - 1530-6992
pISSN - 1530-6984
DOI - 10.1021/nl2020697
Subject(s) - graphene , materials science , variable range hopping , irradiation , electron , graphene nanoribbons , optoelectronics , cathode ray , electron beam processing , nanotechnology , range (aeronautics) , band gap , nanostructure , composite material , physics , thermal conduction , quantum mechanics , nuclear physics
We demonstrate the possibility to selectively reduce insulating fluorinated graphene to conducting and semiconducting graphene by electron beam irradiation. Electron-irradiated fluorinated graphene microstructures show 7 orders of magnitude decrease in resistivity (from 1 TΩ to 100 kΩ), whereas nanostructures show a transport gap in the source-drain bias voltage. In this transport gap, electrons are localized, and charge transport is dominated by variable range hopping. Our findings demonstrate a step forward to all-graphene transparent and flexible electronics.

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