Spectroscopic Evidence of Phase Transition of Monomolecular Water in Solid Polystyrene | Zendy

Makoto GemmeiIde | Zendy; Hiromi Kitano | Zendy

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Spectroscopic Evidence of Phase Transition of Monomolecular Water in Solid Polystyrene

Author(s) -

Makoto GemmeiIde,

Hiromi Kitano

Publication year - 2008

Publication title -

the journal of physical chemistry b

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.864

H-Index - 392

eISSN - 1520-6106

pISSN - 1520-5207

DOI - 10.1021/jp711697e

Subject(s) - polystyrene , sublimation (psychology) , polymer , fourier transform infrared spectroscopy , materials science , phase transition , infrared spectroscopy , chemical engineering , water vapor , analytical chemistry (journal) , polymer chemistry , chemistry , thermodynamics , organic chemistry , composite material , psychology , physics , engineering , psychotherapist

Phase transition behavior of monomolecular water in solid polystyrene was examined by temperature variable Fourier transform infrared spectroscopy. Spectral changes showed for the first time that monomolecular water in a polymer matrix (in a closed system) could be condensed and then frozen and also that the ice formed could be grown and diminished by vapor deposition in cooling process and sublimation in heating process, respectively.

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