Energy-Efficient Green Catalysis: Supported Gold Nanoparticle-Catalyzed Aminolysis of Esters with Inert Tertiary Amines by C–O and C–N Bond Activations | Zendy

YongSheng Bao | Zendy; Menghe Baiyin | Zendy; Agula Bao | Zendy; Meilin Jia | Zendy; Bao Zhaorigetu | Zendy

Open Access

Energy-Efficient Green Catalysis: Supported Gold Nanoparticle-Catalyzed Aminolysis of Esters with Inert Tertiary Amines by C–O and C–N Bond Activations

Author(s) -

YongSheng Bao,

Menghe Baiyin,

Agula Bao,

Meilin Jia,

Bao Zhaorigetu

Publication year - 2014

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/jo500877m

Subject(s) - aminolysis , catalysis , inert , chemistry , colloidal gold , nanoparticle , aryl , organic chemistry , combinatorial chemistry , nanotechnology , materials science , alkyl

Catalyzed by supported gold nanoparticles, an aminolysis reaction between various aryl esters and inert tertiary amines by C-O and C-N bond activations has been developed for the selective synthesis of tertiary amides. Comparison studies indicated that the gold nanoparticles could perform energy-efficient green catalysis at room temperature, whereas Pd(OAc)2 could not.

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