Spontaneous Supramolecular Polymerization Driven by Discrete Platinum Metallacycle-Based Host–Guest Complexation | Zendy

Bingbing Shi | Zendy; Zhixuan Zhou | Zendy; Ryan T. VanderLinden | Zendy; JianHong Tang | Zendy; Guocan Yu | Zendy; Koushik Acharyya | Zendy; Hajar Sepehrpour | Zendy; Peter J. Stang | Zendy

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Spontaneous Supramolecular Polymerization Driven by Discrete Platinum Metallacycle-Based Host–Guest Complexation

Author(s) -

Bingbing Shi,

Zhixuan Zhou,

Ryan T. VanderLinden,

JianHong Tang,

Guocan Yu,

Koushik Acharyya,

Hajar Sepehrpour,

Peter J. Stang

Publication year - 2019

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.9b06181

Subject(s) - metallacycle , supramolecular chemistry , platinum , chemistry , polymerization , polymer chemistry , nanotechnology , combinatorial chemistry , stereochemistry , polymer , molecule , organic chemistry , materials science , physics , catalysis , x ray crystallography , optics , diffraction

Considerable progress in platinum metallacycle-based supramolecular polymerization has promoted the fabrication and application of supramolecular materials. However, despite recent advances, supramolecular polymers constructed through platinum metallacycle-based host-guest complexation remain rare because of the dynamics of platinum metallacycles. Here, we achieve linear supramolecular polymerization via platinum metallacycle-based host-guest complexation by following the design rule of suppressing the dynamics of the metallacycles. The establishment of the platinum metallacycle-based host-guest system and the realization of this type of supramolecular polymerization are expected to open opportunities for platinum metallacycle-based functional materials.

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