Topology-Driven Reductive Silylation of Synthetic Carbon Allotropes | Zendy

Kathrin C. Knirsch | Zendy; Ferdinand Hof | Zendy; Vicent Lloret | Zendy; Udo Mundloch | Zendy; Frank Hauke | Zendy; Andreas Hirsch | Zendy

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Topology-Driven Reductive Silylation of Synthetic Carbon Allotropes

Author(s) -

Kathrin C. Knirsch,

Ferdinand Hof,

Vicent Lloret,

Udo Mundloch,

Frank Hauke,

Andreas Hirsch

Publication year - 2016

Publication title -

journal of the american chemical society

Language(s) - Uncategorized

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.6b09487

Subject(s) - chemistry , silylation , carbon fibers , topology (electrical circuits) , combinatorial chemistry , nanotechnology , organic chemistry , catalysis , algorithm , materials science , mathematics , combinatorics , composite number , computer science

Herein, the combined application of characterization tools, such as Raman spectroscopy, thermal gravimetric analysis coupled with mass spectrometry, and optical and atomic force microscopy, confirms the reductive silylation of synthetic carbon allotropes as a new covalent functionalization strategy for the formation of heteroatom-carbon bonds. In particular, our study gives interesting insights into the topology-driven retrofunctionalization of nanotubide and graphenide derivatives.

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